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Trigonox 101 DHBP organic peroxide for polymer crosslinking and CR-PP applications
Product Overview

Trigonox 101 – 2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane is a bifunctional dialkyl peroxide widely utilized as a polymerization initiator and crosslinking agent. It plays a crucial role in modifying the rheology of polypropylene (CR-PP) and in the crosslinking of various elastomers. This compound is a colorless to light yellow liquid, offering high purity and stability under recommended storage conditions.

Common Names
  • Chemical Name: 2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane

  • CAS Number: 78-63-7

  • Synonyms and Trade Names:

    • Trigonox® 101Nouryon

    • DHBPUnited Initiators

    • Enox® 101Vesta Chemicals

    • Varox® DBPH-50-HPVanderbilt Chemicals

    • Luperox® 101 – Arkema
Technical Specifications
Property Specification
Appearance Colorless to light yellow liquid
Purity (GC) ≥94% w/w
Molecular Weight 290.4 g/mol
Density (20°C) 0.870 – 0.875 g/cm³
Refractive Index (20°C) 1.420 – 1.425
Flash Point 68°C
Decomposition Temperature 140–150°C (medium rate)
Solubility Insoluble in water
UN Number UN 3103
Hazard Class 5.2 (Organic peroxide type C, liquid)
Storage Temperature Below 30°C
Note: The above specifications are provided for reference purposes only. For precise and up-to-date technical details, please contact our marketing team.
Key Benefits
  • Efficient initiator for polymerization and crosslinking processes.

  • Enhances control over polymer melt flow index (MFI).

  • Suitable for a wide range of elastomers and thermoplastics.

  • Stable under recommended storage conditions.

Applications
  • Controlled rheology polypropylene (CR-PP) production.

  • Crosslinking of natural and synthetic rubbers (e.g., EPDM, silicone rubber, HNBR Rubber).

  • Initiator for (co)polymerization of acrylates and methacrylates.

  • Degradation agent for polypropylene to adjust MFI.

Recommended Dosage

Dosage levels vary depending on the specific application and processing conditions.

Disclaimer: Users must consult technical datasheets and conduct preliminary trials to determine the optimal concentration for their specific use case.

Available Pack Sizes
  • 1 kg (Repacked for trials and R&D)

  • 25 kg

Storage Conditions
  • Store in a cool, dry, and well-ventilated area away from sources of heat, ignition, and direct sunlight.

  • Keep containers tightly closed.

  • Avoid contact with reducing agents, acids, alkalis, and heavy metal compounds.

  • Refer to the Safety Data Sheet (SDS) for detailed information.

Citations

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